Organometallic chemistry and homogeneous catalysis (MHC)

Vakbeschrijving Organometallic chemistry and homogeneous catalysis (MHC)
Collegejaar: 2017-2018
Studiegidsnummer: 4423ORGHO (MHC)
Docent(en):
  • Prof. dr. E. Bouwman
Voertaal: Engels
Blackboard: Ja
EC: 6
Niveau: 500
Periode: Semester 2, Blok III
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Organometallic chemistry and homogeneous catalysis
Up to date schedule information

Core course in MSc Chemistry – Energy and Sustainability, elective course in MSc Chemistry

Admission requirements

BSc in MST with a major in Chemistry. Other candidates should have a solid background in coordination chemistry.

Description

The course starts with the fundamental principles of coordination and organometallic chemistry: electron counting, stability and reactivity, reaction mechanisms, steric and electronic influence of the ligands on reactivity of the metal centers. In the second part of the course this knowledge will be used in the discussion of various homogeneously catalysed reactions, notably double bond isomerisation, (enantioselective) hydrogenation, hydroformylation, hydrocarboxylation, oligo- and polymerisation and alkene methathesis.

At the end of the course students:
• will have knowledge of fundamental principles of organometallic chemistry
• will have knowledge of the fundamental principles of homogeneous catalysis
• will have an overview of the applications of homogeneous catalysis in industrial processes and academic research
• will have knowledge of the principles of atom-efficiency and sustainable chemistry
• will be able to construct a mechanism of various homogeneously catalysed reactions.
• will be able to construct tentative catalytic mechanisms also for reactions that were not discussed
• can digest and present a summary of a scientific article from the literature

Mode of instruction

Lectures and exercises

Language

English

Timetable

Schedule information can be found on the website of the programmes.

Literature

The course is based on the following book:
R.H. Crabtree, The Organometallic Chemistry of the Transition Metals, Wiley Interscience (5th Ed: ISBN: 978-0-470-25762-3, or 6th Ed: ISBN: 978-1-118-13807-6).
Slides presented during the courses
Excercises

Examination

Written examination (100%)

Contact Information

Information about the Lecturer

Registration

Register for this course via uSis
For more information on how to sign up for classes

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